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Chemical syntheses and properties of hydroxycinnamoyl-coenzyme A derivatives

策马入林添加于 2014-11-12 15:10 | 1436 次阅读 | 0 个评论

作者
Stockigt J, Zenk MH
摘要
Acyl-CoA derivatives of several hydroxylated cinnamic acids have been synthesized in 30 to 50% yield via a. acyl phenyl thiol esters, b. acyl N-hydroxysuccinimide esters, and c. glucocinnamoyl derivatives. Properties of the intermediates have been determined. The cinnamyol-CoA thiol esters were characterized by their chromatographic behaviour and UV spectra. The molar extinction coefficients of these important intermediates in plant phenylpropane metabolism have been unequivocally determined. Recently published values 13 for the molar extinction coefficients of these derivatives are incorrect; the methodological reason for this error has been established.
详细资料
- 关键词: Chemical Phenomena; Chemistry; *Cinnamates/chemical synthesis; Coenzyme A/chemical synthesis
- 文献种类:期刊
- 期刊名称: Zeitschrift fur Naturforschung. Section C: Biosciences
- 期刊缩写: Z Naturforsch C
- 期卷页: 1975年第30卷第3期 352-358页
- ISBN: 0341-0382
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